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How could I fiddle with old, rusty Z's for 15 years and not know about Electrolytic Rust Removal? Someone else mentioned it here, I Googled it and studied these articles:
Electrolytic Rust Removal
http://www3.telus.net/public/aschoepp/electrolyticrust.html
http://www.buchanan1.net/rust.shtml
Electrolysis Rust Removal
http://www.htpaa.org.au/article-electro.php
The process was cheap, didn't require any nasty chemicals, didn't produce any nasty chemicals, and seemed to produce good results, and since I have no shortage of old rusty Z parts lying around, I decided to give it a try.
I went to the grocery store and bought a box of washing powder, which is simply sodium carbonate. Some of the sites say you can use baking soda (sodium bicarbonate) but I didn't find any articles where anyone had tried it. Basically, all the sodium carbonate does is make the water conduct electricity better. Then I bought a sheet of 22 gauge steel from the hardware store (it must NOT be galvanized/zinc coated). Some people use rebar. Don't spend a lot of money on your electrode--it will eventually get eaten away in this process. Also you don't want to use stainless steel because it can create hazardous insoluble hydroxides or oxides. I filled a 5-gallon bucket with water and pulled out the battery charger. Then I selected a nicely rusted brake rotor.
I put roughtly 5 tablespoons of washing powder in the bucket and stirred it up. I bent the steel sheet to fit the curve of the bucket and inserted it so that a few inches stuck out above the water. I put the rotor in the bucket so that it was a couple of inches away from the steel sheet. The rotor just barely fit in the bucket, so I was sure it wasn't going to move. Later I clamped the steel sheet to the side of the bucket.
I moved all of this outside to the garage stoop. You want to do this in a well ventilated area because this process is going to release pure oxygen and hydrogen. Don't smoke around this! I left the battery charger just inside the garage door and stretched the leads outside so I could hook the battery clamps up to the rotor and the steel sheet.
I checked the article once more before I switched on the charger...GOOD THING! Did you catch what is wrong in the picture above? I reversed the wires! You want to put the NEGATIVE terminal on the rusty piece and the POSITIVE terminal on the steel sheet or electrode. If I had left it this way for very long, my positive battery charger clamp would have gotten eaten away. You want your rusty piece to be submerged in the water and it's ok if your (negative) charger clamp is partially submerged. You don't want your positive charger clamp on your electrode (steel sheet) to be under the water.
I put the charger on 6V and plugged her in. Immediately it showed a 2 amp draw. In just a minute bubbles started rising off of the rotor and the steel sheet. The bubbles coming off the rotor are hydrogen and the bubbles coming off the electrode are oxygen.
I left it outside overnight. When I checked it in the morning the water had turned rust-colored and had rust-colored foam on top. I unplugged the charger and unclamped the leads.
I looked at the steel sheet. It was covered with thick black stuff--oxide. I pulled out the brake drum, hosed it off and scrubbed it with a plastic brush. Then I dried it off with a paint dryer. Sure enough, the rust was almost completely gone! Almost, but not completely. So I pulled out my drill/wire disc and worked on it. It didn't take much effort at all to make it shine. Now, it looked a lot better!
It still looks a little darker than you'd expect brand new steel to look. I think part of that is from oxidation in the process. The amazing thing is that it seems like every flaw in the rotor now stands out like a sore thumb.
My now-rust-free rotor is now extremely rust-prone so I applied some Sherwin Williams Ultra Clean and later I might shoot some WD40 on it.
My rotor is rust-free on only one side. This process only removes rust for the parts of the rotor that could "see" the steel sheet. This is because the electrons take a direct path from the electrode to surface of the rusty piece. I'll have to turn the rotor over and treat the other side.
Overall, I'm pretty pleased with this process and I'll use it on as many parts as I can. I want to do some more research before applying this to stressed parts like suspension pieces. I've read that this process can cause hydrogen embrittlement--some of the hydrogen goes into the metal. It's possible that the hydrogen can be released by baking the piece afterwards for a few hours in a 200-degree oven, but don't take my word for that. And I'm assuming you don't want to even think about doing this for internal engine parts.
Next, I have an incredibly rusty oil pan I'm going to treat. Also, I'm going to figure out how to set up the old plastic kiddie pool to de-rust larger parts.
And if I can just figure out who will let me drive my stripped chassis into their swimming pool and how much washing soda it would take to treat my entire car...
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